PRODUCT .

Polyurethane.

Product

The polyurethane business of Ad-Winner is segmented into the Polyester Polyol, TPU for forming, TPU for coating and TPU for adhesion.
Ad-Winner supplies Polyol, K series as a brand name, applied to synthetic leathers, paints, shoes and elastomers with the K series and consolidates the foundation of major industries such as shoes, automotives, architecture and leisure through TPU resin named NEOSTANE, NEOTHANE and NEOTIE.
With more advanced total marketing through creative and innovative product development, Ad-Winner identifies the customers' needs in advance and so leads the future of polyurethane.

  • Capacity

    • Polyester Polyol 20,000MT/year
    • TPU for Molding 8,500MT/year
    • TPU for Adhesion 4,500MT/year
    • Aliphatic TPU 8,000MT/year

POLYOL.

K Series

K Series applying in the Polyurethane reaction are hydroxyl terminated Polyester diols made from Adipic acid and several glycols and used as base materials of synthetic leather, paint, sole, elastomer etc.

Product Molecular
weight (g/mol)		 OH Value
(mgKOH/g)		 Acid value
(mgKOH/g)		 Viscosity
(60℃/cps)		 Moisture
(%)		 Color
(APHA No.)		 Component
K - 240 1,000 - ± 5% 112.20 - ± 5% < 0.5 About 420 < 0.03 < 50 AA/1.4BG
K - 250 2,000 - ± 5% 56.10 - ± 5% < 0.5 About 1,300 < 0.03 < 50 AA/DEG
K - 300 2,000 - ± 5% 56.10 - ± 5% < 0.5 About 1,400 < 0.03 < 50 AA/EG
K - 320 2,000 - ± 5% 56.10 - ± 5% < 0.5 About 1,740 < 0.03 < 50 AA/1,4BG
K - 340L 1,500 - ± 5% 74.80 - ± 5% < 0.5 About 600 < 0.03 < 50 AA/EG/1,4BG
K - 340H 2,000 - ± 5% 56.10 - ± 5% < 0.5 About 1,550 < 0.03 < 50 AA/EG/1,4BG
K - 350M 2,200 - ± 5% 51.00 - ± 5% < 0.5 About 2,300 < 0.03 < 50 AA/1,3PDO
K - 360L 1,410 - ± 5% 79.57 - ± 5% < 0.5 About 730 < 0.03 < 50 AA/EG/DEG
K - 360H 2,000 - ± 5% 56.10 - ± 5% < 0.5 About 1,380 < 0.03 < 50 AA/EG/DEG
K - 400L 2,000 - ± 5% 56.10 - ± 5% < 0.5 About 3,000 < 0.03 < 100 AA/NPG
K - 480 2,250 - ± 5% 49.87 - ± 5% < 0.5 About 2,700 < 0.03 < 50 AA/1,6HG
K - 2208 2,000 - ± 5% 56.10 - ± 5% < 0.5 About 1,800 < 0.03 < 50 AA/1.4BG/1.6HG
PE-2000MP 2,000 - ± 5% 56.10 - ± 5% < 0.5 About 1,150 < 0.03 < 50 AA/MPG
K-P320 335 - ± 5% 335 - ± 5% 1.5 ~ 1.99 1,900 ~ 2,400(25℃) < 0.05 < 100 PA/DEG

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NEOTHANE.

  • 5000 Series

    Properties Test Method Units 5000 Series
    5075AP 5080AP 5085AP 5090AP 5095AP 5098AP 5068DP
    Hardness ASTM D 2240 Shore A/D 77 ± 3 84 ± 3 86 ± 3 93 ± 3 96 ± 3 55 ± 3
    (Shore D)    		 68 ± 3
    (Shore D)
    Specific Gravity ASTM D 792 1.15~1.21 1.20~1.22 1.20~1.22 1.22~1.24 1.22~1.24 1.23~1.25 1.23~1.25
    100% Modulus ASTM D 412 Kgf/㎠ Min. 30 Min. 50 Min. 50 Min. 80 Min. 110 Min. 140 Min. 200
    300% Modulus ASTM D 412 Kgf/㎠ Min. 50 Min. 100 Min. 100 Min. 110 Min. 200 Min. 220 Min. 300
    Tensile Strength ASTM D 412 Kgf/㎠ Min. 250 Min. 350 Min. 350 Min. 400 Min. 400 Min. 400 Min. 400
    Tear Strength ASTM D 624 Kgf/㎝ Min. 85 Min. 100 Min. 80 Min. 110 Min. 130 Min. 140 Min. 200
    Elongation ASTM D 412 % Min. 450 Min. 500 Min. 450 Min. 450 Min. 400 Min. 400 Min. 300
    Melt Flow Index ASTM D 1238 g/10min. 5~10 5~15 5~20 5~20 5~20 5~20 10~30
    ※ Melt Flow Index Conditions : A℃×Bkg
    (Pre-rying :10min,100℃)    		 190℃
    ×2.16kg    		 210℃
    ×2.16kg    		 207℃
    ×5.00kg    		 207℃
    ×2.16kg    		 210℃
    ×2.16kg    		 215℃
    ×2.16kg    		 220℃
    ×2.16kg

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    Process Extrusion ○ ○ ○ ○ ○ ○
    Injection ○ ○ ○ ○ ○ ○ ○
    Type (Ester,Ether, etc.) Polyester
    Appearance Pellet, Clear
    Application General ○ ○ ○ ○ ○ ○ ○
    Film
    Hose ○ ○ ○ ○
    Cable
    Compound(PVC, POM etc.) ○ ○ ○ ○
    Air bag
    Hotmelt film
    Specialty Transparency
    Heat resistance
    Cold resistance
    Hydrolysis resistance
    High Freuency cutting
    Non-yellowish

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  • 5100 Series

    Properties Test Method Units 5100 Series High Elongation
    5185AP 5190AP 5195AP 5198AP 5160DP 5175DP 5178DP
    Hardness ASTM D 2240 Shore A/D 87 ± 3 93 ± 3 95 ± 3 57 ± 3
    (Shore D)    		 65 ± 3
    (Shore D)    		 72 ± 3
    (Shore D)    		 75 ± 3
    (Shore D)
    Specific Gravity ASTM D 792 1.18~1.22 1.20~1.22 1.20~1.22 1.21~1.25 1.22~1.26 1.22~1.26 1.22~1.26
    100% Modulus ASTM D 412 Kgf/㎠ Min. 60 Min. 100 Min. 100 Min. 130 Min. 200 Min. 200 Min. 200
    300% Modulus ASTM D 412 Kgf/㎠ Min. 80 Min. 180 Min. 180 Min. 220 Min. 300 Min. 300 -
    Tensile Strength ASTM D 412 Kgf/㎠ Min. 210 Min. 400 Min. 400 Min. 400 Min. 400 Min. 350 Min. 350
    Tear Strength ASTM D 624 Kgf/㎝ Min. 80 Min. 120 Min. 120 Min. 150 Min. 200 Min. 220 Min. 275
    Elongation ASTM D 412 % Min. 550 Min. 400 Min. 400 Min. 375 Min. 300 Min. 350 Min. 250
    Melt Flow Index ASTM D 1238 g/10min. 10~25 5~25 5~25 25~45 5~15 20~30 20~30
    ※ Melt Flow Index Conditions : A℃×Bkg
    (Pre-rying :10min,100℃)    		 210℃
    ×2.16kg    		 208℃
    ×5.00kg    		 210℃
    ×2.16kg    		 210℃
    ×5.00kg    		 215℃
    ×5.00kg    		 230℃
    ×2.16kg    		 230℃
    ×2.16kg

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    Process Extrusion ○ ○ ○ ○
    Injection ○ ○ ○ ○ ○ ○ ○
    Type (Ester,Ether, etc.) Polyester
    Appearance Pellet, Clear
    Application General ○ ○ ○ ○ ○ ○ ○
    Film ○ ○ ○
    Hose ○ ○
    Cable
    Compound(PVC, POM etc.)
    Air bag ○ ○ ○
    Hotmelt film
    Specialty Transparency ○ ○ ○ ○ ○ ○ ○
    Heat resistance
    Cold resistance
    Hydrolysis resistance ○ ○ ○ ○
    High Freuency cutting
    Non-yellowish

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  • 5700 - 5100 Series

    Properties Test Method Units Product Grade
    5185X 5195X 5285AP 5385AP 5395AP 5485AP 5490AP 5790AP
    Hardness ASTM D 2240 Shore A/D 88 ± 3 96 ± 3 85 ± 3 90 ± 3 97 ± 3 87 ± 3 92 ± 3 92 ± 3
    Specific Gravity ASTM D 792 1.20~1.22 1.20~1.22 1.19~1.21 1.19~1.21 1.22~1.24 1.20~1.22 1.20~1.22 1.20~1.22
    100% Modulus ASTM D 412 Kgf/㎠ Min. 65 Min. 100 Min. 40 Min. 65 Min. 130 Min. 65 Min. 80 Min. 80
    300% Modulus ASTM D 412 Kgf/㎠ Min. 100 Min. 180 Min. 70 Min. 100 Min. 200 Min. 100 Min. 130 Min. 150
    Tensile Strength ASTM D 412 Kgf/㎠ Min. 400 Min. 400 Min. 200 Min. 400 Min. 400 Min. 400 Min. 400 Min. 400
    Tear Strength ASTM D 624 Kgf/㎝ - Min. 120 Min. 80 Min. 100 Min. 130 Min. 100 Min. 120 Min. 100
    Elongation ASTM D 412 % Min. 500 Min. 400 Min. 500 Min. 450 Min. 400 Min. 450 Min. 400 Min. 400
    Melt Flow Index ASTM D 1238 g/10min. - - 10~20 15~45 20~60 20~40 25~35 10~30
    ※ Melt Flow Index Conditions : A℃×Bkg
    (Pre-rying :10min,100℃)    		 - - 185℃
    ×2.16kg    		 207℃
    ×5.00kg    		 210℃
    ×5.00kg    		 207℃
    ×5.00kg    		 210℃
    ×5.00kg    		 208℃
    ×5.00kg

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    Process Extrusion ○ ○ ○ ○ ○ ○ ○
    Injection ○ ○ ○ ○ ○ ○ ○ ○
    Type (Ester,Ether, etc.) Polyester
    Appearance Pellet, Clear
    Application General ○ ○ ○ ○ ○ ○
    Film ○ ○ ○ ○ ○
    Hose
    Cable
    Compound(PVC, POM etc.)
    Air bag ○
    Hotmelt film
    Specialty Transparency ○ ○
    Heat resistance
    Cold resistance ○
    Hydrolysis resistance
    High Freuency cutting ○
    Non-yellowish

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  • 6100 - 5800 Series

    Properties Test Method Units Product Grade
    5885AP 4095AP 6175AP 6185AP 6193AP 6198AP 6164DP
    Hardness ASTM D 2240 Shore A/D 86 ± 3 95 ± 3 78 ± 3 85 ± 3 92 ± 3 53 ± 3
    (Shore D)    		 68 ± 3
    (Shore D)
    Specific Gravity ASTM D 792 1.20~1.21 1.20~1.22 1.08~1.10 1.09~1.11 1.10~1.12 1.10~1.12 1.12~1.14
    100% Modulus ASTM D 412 Kgf/㎠ Min. 50 Min. 100 Min. 40 Min. 50 Min. 90 Min. 120 Min. 250
    300% Modulus ASTM D 412 Kgf/㎠ Min. 80 Min. 200 Min. 80 Min. 100 Min. 150 Min. 180 Min. 350
    Tensile Strength ASTM D 412 Kgf/㎠ Min. 300 Min. 400 Min. 300 Min. 350 Min. 400 Min. 400 Min. 400
    Tear Strength ASTM D 624 Kgf/㎝ Min. 80 Min. 130 Min. 70 Min. 80 Min. 110 Min. 150 Min. 180
    Elongation ASTM D 412 % Min. 500 Min. 450 Min. 500 Min. 500 Min. 420 Min. 400 Min. 250
    Melt Flow Index ASTM D 1238 g/10min. 10~20 1~15 5~20 10~20 1~15 1~20 15~35
    ※ Melt Flow Index Conditions : A℃×Bkg
    (Pre-rying :10min,100℃)    		 205℃
    ×2.16kg    		 210℃
    ×2.16kg    		 195℃
    ×5.00kg    		 190℃
    ×10.00kg    		 210℃
    ×2.16kg    		 215℃
    ×2.16kg    		 220℃
    ×2.16kg

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    Process Extrusion ○ ○ ○ ○ ○
    Injection ○ ○ ○ ○ ○ ○ ○
    Type (Ester,Ether, etc.) Polyester      Polycaprolactone      Polyether
    Appearance Pellet, Clear
    Application General ○ ○ ○ ○
    Film ○ ○
    Hose ○ ○ ○
    Cable ○ ○ ○ ○
    Compound(PVC, POM etc.) ○ ○ ○
    Air bag
    Hotmelt film
    Specialty Transparency ○ ○ ○ ○ ○
    Heat resistance ○
    Cold resistance ○ ○ ○ ○ ○
    Hydrolysis resistance ○ ○ ○ ○ ○
    High Freuency cutting
    Non-yellowish

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  • 7000 Series

    Properties Units Product Grade
    7010H 7020H 7030H 7320H
    Hardness Shore A 75 ± 2 80 ± 2 80 ± 2 90 ± 2
    Specific Gravity 1.13 1.19 1.19 1.2
    MELT INDEX(175℃,195°C X 2.16kg) g/10min. 10~15 10~15 4~8 10~20
    FLOW BEGINNING TEMPERATURE ℃ 90 ± 5 110 ± 5 120 ± 5 105 ± 5
    Tg(GLASS TRANSITION TEMPERATURE) ℃ -25 -20 -20 -5
    Tm(Temperature of fusion) ℃ 105 ± 5 120 ± 5 120 ± 5 110 ± 5

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    Process Extrusion ○ ○ ○ ○
    Injection
    Type (Ester,Ether, etc.) Polyester
    Appearance Pellet, Clear
    Application General
    Film
    Hose
    Cable
    Compound(PVC, POM etc.)
    Air bag
    Hotmelt film ○ ○ ○ ○
    Specialty Transparency
    Heat resistance
    Cold resistance
    Hydrolysis resistance
    High Freuency cutting
    Non-yellowish

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    Suggested Start-up conditions Extrusion Process
    PRODUCT Dies Zone(℃) Adapter(℃) Barrel Zone 4(℃) Barrel Zone 3(℃) Barrel Zone 2(℃) Barrel Zone 1(℃)
    7010H 165 ± 5 160 ± 5 155 ± 5 150 ± 5 140 ± 5 80 ± 5
    7020H / 7030H 175 ± 5 170 ± 5 165 ± 5 160 ± 5 150 ± 5 90 ± 5
    7320H 195 ± 5 195 ± 5 190 ± 5 185 ± 5 180 ± 5 175 ± 5

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  • Other Series

    Properties Test Method Units 1200 Series
    NCO Rich    		 Product Grade
    1285AP 1680AP 1690AP 1698AP 1660AP
    Hardness JIS K-7311
    ASTM D 2240    		 Shore A
    Shore D    		 88 ± 3 84 ± 3 92 ± 3 98 ± 3
    60 ± 3    		 63 ± 3
    Density JIS K-7311
    ASTM D 792    		 g/㎤ 1.20 1.22 1.23 1.26 1.27
    100% Modulus JIS K-7311
    ASTM D 412    		 kg/㎠ 60 50 97 175 225
    Tensile Strength JIS K-7311
    ASTM D 412    		 kg/㎠ > 400 > 300 > 400 > 400 > 450
    Elongation JIS K-7311
    ASTM D 412    		 % > 450 > 500 > 450 > 350 > 300
    Tear Strength JIS K-7311
    ASTM D 412    		 kg/cm > 100 > 70 > 110 > 150 > 180
    Softening Point JIS K-7311
    ASTM D 412    		 ℃ 85 75 85 95 105
    Taber Abrasion
    (H18 wheel, 1kg Load)    		 JIS K-7311
    ASTM D 1044    		 mg/1000
    Cycle    		 25 30 33 36 39
    Rebound Resilience JIS K-7311
    ASTM D 2632    		 % 32 35 35 32 30
    Mold Shrinkage ASTM D 955 m/m 0.0045 0.0060 0.0045 0.0045 0.0040
    Chemical structure Based on Polyester Polyol
    User Processing method Injection : NEOTHANE 1285AP, 1680AP~1660DP

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APPLICATION

Shoe Part

  • NEOTHANE 5185AP

  • NEOTHANE 5690AP

  • NEOTHANE 5160DP

  • NEOTHANE 5160DP

  • NEOTHANE 5198AP

Outsole and Air-bag

Air-bag: NEOTHANE 5190AP
Outsole: NEOTHANE 5690AP/5695AP

Industry (Golf Ball, Oil Seal, Link Seal)

  • NEOTHANE 6303D

  • NEOTHANE 4095AP

  • NEOTHANE 5098AP

Hoses, Tubing, Cable

  • NEOTHANE 5190AP/5195AP

  • NEOTHANE 6185AP

Automobile & Robot Sensor Cable

  • NEOTHANE 6175AP, 6185AP

Goggles Frame

  • NEOTHANE 5385AP

High Frequency

  • NEOTHANE 5285AP/5790AP

Sheet, Film

  • NEOTHANE 5485AP/5395AP

PSM TPU Physical Properties

NEOSTANE is the trade name for thermoplastic polyurethanes (TPU) as a non-yellowish type produced by Ad-Winner, which has the great performance with heat and UV resistance and is suitable for Injection, Extrusion and PSM process.

Properties Test Method Units STA77N slush skin layer
Specific Gravity ASTM D 792 g/㎤ 1.13
Hardness ASTM D 2240 Shore A 77
Tensile Strength ASTM D 412 kgf/㎠ 180
Elongation ASTM D 412 % 850
Tear Strength ASTM D 624 kgf/cm 70
MFI ISO 1133 g/10min
(165℃, 2.16kg load)		 55
Heat resistance MS 256-29 △ E 0.62
Weather-O-meter MS 256-29 △ E 0.70
Outdoor Test Q-Lab Arizona, GM 9538P
(100,000 SASR Langleys)		 △ E AVERAGE 0.95
Hydrolysis
(Tensile Strength)		 MS 300-31 85℃, 98% RH, 168H -7%
Solvent resistance Very Good

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STA77N

Automotive Material - PSM (Powder Slush Molding)

TPU development For automobile
  • Joint development of TPU for automobile with Hyundai Mobis
  • Material patent : DSHC
  • Molding patent : Bilateral retention
Technical Advantage
  • Higher emotional quality in smell and touch
  • Excellent Air-bag unfolding
  • Environmentally friendly material for recycling PVC causes Dioxin in incineration
  • Excellent durability
Applied Model
  • Applied to interior materials with good touch and luxury design for mid and luxury sedan

  • TPU Powder

  • Instrument Panel

  • Console

  • Door Trim

Automotive Instrument Panel Skin
  • Good Elasticity in Low temperature
  • Excellent Light Resistant & Heat Resistant without Coatings
  • Narrow Particle Size Distribution Make Excellent Powder Flow
  • Existing Slush Molding Equipment Is Available
PSM (Powder Slush Molding) Process
Soft Type IN-PANEL (Skin, Foam, Core)

  • Skin (PVC, ABS, TPO, TPU)

  • Foam (URETHANE)

  • Core (PC+ABS, PP)

9100 - 9000 Series

Properties Test Method Units Product Grade
9094AP 9180AP 9190AP
Hardness ASTM D 2240 Shore A/D 95 ± 1 84 ± 2 89
Specific Gravity ASTM D 792 1.14 1.13 1.125
100% Modulus ASTM D 412 Kgf/㎠ Min. 80 Min. 50 60
300% Modulus ASTM D 412 Kgf/㎠ Min. 150 Min. 65 80
Tensile Strength ASTM D 412 Kgf/㎠ Min. 300 Min. 200 420
Tear Strength ASTM D 624 Kgf/㎝ Min. 100 Min. 65 130
Elongation ASTM D 412 % Min. 500 Min. 800 750
Melt Flow Index ASTM D 1238 g/10min. 1~6 50~65 12
※ Melt Flow Index Conditions : A℃×Bkg
(Pre-rying :10min,100℃)		 175℃
×2.16kg		 160℃
×2.16kg		 190℃
×2.16kg

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Process Extrusion ○ ○ ○
Injection ○ ○ ○
Type (Ester,Ether, etc.) Polyester-ether
Appearance Pellet, Clear
Application General
Film ○ ○ ○
Hose
Cable
Compound(PVC, POM etc.)
Air bag
Hotmelt film
Specialty Transparency ○ ○ ○
Heat resistance
Cold resistance ○ ○ ○
Hydrolysis resistance ○ ○ ○
High Freuency cutting
Non-yellowish ○ ○ ○

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SPF Physical Properties

Properties Test Method Units SPF
Specific Gravity ASTM D 792 g/㎤ 1.14
Hardness ASTM D 2240 Shore A 93 - 95
Tensile Strength ASTM D 412 kgf/㎠ > 550
Elongation ASTM D 412 % > 400
Transmittance ASTM D 1003 % > 90
Haze ASTM D 1003 % < 1.5
Gloss ASTM D 563 GU > 95
UV resistance 50℃, UV A(0.78W/m²), 1000hrs △ E < 1.0

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SPF

NEOTIE.

Physical Properties

Properties Specific
Gravity		 Viscosity
(15% MEK 20℃)		 Crystallization
Rate		 Thermo
plasticity		 Hydrolysis
resistance		 Solvents
NEOTIE 3202 1.23 200~600 mPa.s High High Good MEK, EA, Acetone, M.C, THF
NEOTIE 3202H 1.23 1000~2000 mPa.s High High Good MEK, EA, Acetone, M.C, THF
NEOTIE 3202R 1.23 100↓ mPa.s High High Good M.C, MEK, EA, Acetone, THF
NEOTIE 3208 1.23 950~1450 mPa.s Very High High Good MEK(20%, 25℃), EA, Acetone, M.C, THF
NEOTIE 7204 1.23 1000~1700 mPa.s Middle High Very Good MEK, EA, Acetone, M.C, THF
NEOTIE 7408 1.23 1000~1400 mPa.s Very High Low Very Good MEK, Acetone, THF
NEOTIE 9808 1.23 100↓mPa.s Very High High Good MEK, EA, Acetone, M.C, THF
NEOTIE 9202VH 1.23 2300 ~ 3300 mPa.s Very High High Good MEK, EA, Acetone, M.C, THF
NEOTHANE 3402 1.23 ´Max. 150 mPa.s Very High High Good MEK(20%, 30℃), EA, Acetone, M.C, THF, Toluene

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APPLICATION

  • Adhesive for Shoes

  • Adhesive for Furniture

  • Adhesive for Automotive

  • Adhesive for Textile

CUSTOMERS.